Breaking the Curve with CANDELS: A Bayesian Approach to Reveal the Non-Universality of the Dust-Attenuation Law at High Redshift

Dust attenuation affects nearly all observational aspects of galaxy evolution, yet very little is known about the form of the dust-attenuation law in the distant Universe. Here, we model the spectral energy distributions (SEDs) of galaxies at z = 1.5--3 from CANDELS with rest-frame UV to near-IR imaging under different assumptions about the dust law, and compare the amount of inferred attenuated light with the observed infrared (IR) luminosities. Some individual galaxies show strong Bayesian evidence in preference of one dust law over another, and this preference agrees with their observed location on the plane of infrared excess (IRX, $L_{\text{TIR}}/L_{\text{UV}}$) and UV slope ($\beta$). We generalize the shape of the dust law with an empirical model, $A_{\lambda,\delta}=E(B-V)\ k_\lambda\ (\lambda/\lambda_V)^\delta$ where $k_\lambda$ is the dust law of Calzetti et al. (2000), and show that there exists a correlation between the color excess ${E(B-V)}$ and tilt $\delta$ with ${\delta=(0.62\pm0.05)\log(E(B-V))}$+ ${(0.26~\pm~0.02)}$. Galaxies with high color excess have a shallower, starburst-like law, and those with low color excess have a steeper, SMC-like law. Surprisingly, the galaxies in our sample show no correlation between the shape of the dust law and stellar mass, star-formation rate, or $\beta$. The change in the dust law with color excess is consistent with a model where attenuation is caused by by scattering, a mixed star-dust geometry, and/or trends with stellar population age, metallicity, and dust grain size. This rest-frame UV-to-near-IR method shows potential to constrain the dust law at even higher ($z>3$) redshifts.Comment: 20 pages, 18 figures, resubmitted to Ap

The SFR-M _∗ Correlation Extends to Low Mass at High Redshift

To achieve a fuller understanding of galaxy evolution, SED fitting can be used to recover quantities beyond stellar masses (M$_*$) and star formation rates (SFRs). We use Star Formation Histories (SFHs) reconstructed via the Dense Basis method of Iyer \& Gawiser (2017) for a sample of $17,873$ galaxies at $0.5<z<6$ in the CANDELS GOODS-S field to study the nature and evolution of the SFR-M$_*$ correlation. The reconstructed SFHs represent trajectories in SFR-M$_*$ space, enabling us to study galaxies at epochs earlier than observed by propagating them backwards in time along these trajectories. We study the SFR-M$_*$ correlation at $z=1,2,3,4,5,6$ using both direct fits to galaxies observed at those epochs and SFR-M$_*$ trajectories of galaxies observed at lower redshifts. The SFR-M$_*$ correlations obtained using the two approaches are found to be consistent with each other through a KS test. Validation tests using SFHs from semi-analytic models and cosmological hydrodynamical simulations confirm the sensitivity of the method to changes in the slope, normalization and shape of the SFR-M$_*$ correlation. This technique allows us to further probe the low-mass regime of the correlation at high-z by $\sim 1$ dex and over an effective volume of $\sim 10\times$ larger than possible with just direct fits. We find that the SFR-M$_*$ correlation is consistent with being linear down to M$_*\sim 10^7 M_\odot$ at $z>4$. The evolution of the correlation is well described by $\log SFR= (0.80\pm 0.029 - 0.017\pm 0.010\times t_{univ})\log M_*$ $- (6.487\pm 0.282-0.039\pm 0.008\times t_{univ})$, where $t_{univ}$ is the age of the universe in Gyr.Comment: 22 pages, 10 figures. Accepted for publication in Ap

Stellar Mass--Gas-phase Metallicity Relation at 0.5≤z≤0.70.5\leq z\leq0.7: A Power Law with Increasing Scatter toward the Low-mass Regime

We present the stellar mass ($M_{*}$)--gas-phase metallicity relation (MZR) and its scatter at intermediate redshifts ($0.5\leq z\leq0.7$) for 1381 field galaxies collected from deep spectroscopic surveys. The star formation rate (SFR) and color at a given $M_{*}$ of this magnitude-limited ($R\lesssim24$ AB) sample are representative of normal star-forming galaxies. For masses below $10^9 M_\odot$, our sample of 237 galaxies is $\sim$10 times larger than those in previous studies beyond the local universe. This huge gain in sample size enables superior constraints on the MZR and its scatter in the low-mass regime. We find a power-law MZR at $10^{8} M_\odot < M_{*} < 10^{11} M_\odot$: ${12+log(O/H) = (5.83\pm0.19) + (0.30\pm0.02)log(M_{*}/M_\odot)}$. Our MZR shows good agreement with others measured at similar redshifts in the literature in the intermediate and massive regimes, but is shallower than the extrapolation of the MZRs of others to masses below $10^{9} M_\odot$. The SFR dependence of the MZR in our sample is weaker than that found for local galaxies (known as the Fundamental Metallicity Relation). Compared to a variety of theoretical models, the slope of our MZR for low-mass galaxies agrees well with predictions incorporating supernova energy-driven winds. Being robust against currently uncertain metallicity calibrations, the scatter of the MZR serves as a powerful diagnostic of the stochastic history of gas accretion, gas recycling, and star formation of low-mass galaxies. Our major result is that the scatter of our MZR increases as $M_{*}$ decreases. Our result implies that either the scatter of the baryonic accretion rate or the scatter of the $M_{*}$--$M_{halo}$ relation increases as $M_{*}$ decreases. Moreover, our measures of scatter at $z=0.7$ appears consistent with that found for local galaxies.Comment: 18 pages, 10 figures. Accepted by ApJ. Typos correcte

CANDELS Multi-wavelength Catalogs: Source Detection and Photometry in the GOODS-South Field

We present a UV-to-mid infrared multi-wavelength catalog in the CANDELS/GOODS-S field, combining the newly obtained CANDELS HST/WFC3 F105W, F125W, and F160W data with existing public data. The catalog is based on source detection in the WFC3 F160W band. The F160W mosaic includes the data from CANDELS deep and wide observations as well as previous ERS and HUDF09 programs. The mosaic reaches a 5$\sigma$ limiting depth (within an aperture of radius 0.17 arcsec) of 27.4, 28.2, and 29.7 AB for CANDELS wide, deep, and HUDF regions, respectively. The catalog contains 34930 sources with the representative 50% completeness reaching 25.9, 26.6, and 28.1 AB in the F160W band for the three regions. In addition to WFC3 bands, the catalog also includes data from UV (U-band from both CTIO/MOSAIC and VLT/VIMOS), optical (HST/ACS F435W, F606W, F775W, F814W, and F850LP), and infrared (HST/WFC3 F098M, VLT/ISAAC Ks, VLT/HAWK-I Ks, and Spitzer/IRAC 3.6, 4.5, 5.8, 8.0 $\mu$m) observations. The catalog is validated via stellar colors, comparison with other published catalogs, zeropoint offsets determined from the best-fit templates of the spectral energy distribution of spectroscopically observed objects, and the accuracy of photometric redshifts. The catalog is able to detect unreddened star-forming (passive) galaxies with stellar mass of 10^{10}M_\odot at a 50% completeness level to z$\sim$3.4 (2.8), 4.6 (3.2), and 7.0 (4.2) in the three regions. As an example of application, the catalog is used to select both star-forming and passive galaxies at z$\sim$2--4 via the Balmer break. It is also used to study the color--magnitude diagram of galaxies at 0<z<4.Comment: The full resolution article is now published in ApJS (2013, 207, 24). 22 pages, 21 figures, and 5 tables. The catalogue is available on the CANDELS website: http://candels.ucolick.org/data_access/GOODS-S.html MAST: http://archive.stsci.edu/prepds/candels and Rainbow Database: https://arcoiris.ucolick.org/Rainbow_navigator_public and https://rainbowx.fis.ucm.es/Rainbow_navigator_publi

Recent Synthetic Studies Leading to Structural Revisions of Marine Natural Products

Because of the highly unique structures of marine natural products, there are many examples of structures that were originally proposed based on spectral analyses but later proven incorrect. In many cases, the total syntheses of the originally proposed structures of marine natural products has confirmed their incorrectness and the subsequent total syntheses of the newly proposed structures proved the revised structures. This review will show such cases appearing after 2005 and demonstrate how the true structures were elucidated

Neurophysiology

Contains reports on twenty research projects.Bell Laboratories (Grant)National Institutes of Health (Grant 5 R01 EY01149-03S2)National Institutes of Health (Grant 5 TO1 EY00090-04)National Institutes of Health (Grant 5 RO1 NS12307-03)National Institutes of Health (Grant K04 NS00010)National Multiple Sclerosis Society (Grant RG-1133-A-1)Health Sciences Fund (Grant 78-10